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Observation of the Electrolyte Wetting and 'Unwetting' in Li-Ion Pouch Cells Via Ultrasonic Scanning Technology

22 Pages Posted: 7 May 2020 Publication Status: Published

See all articles by Zhe Deng

Zhe Deng

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology

Zhenyu Huang

Huazhong University of Science and Technology

Yue Shen

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology

Yunhui Huang

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology

Han Ding

Huazhong University of Science and Technology

Aidan Luscombe

Dalhousie University - Department of Physics and Atmospheric Science

Michel Johnson

Dalhousie University - Department of Physics and Atmospheric Science

jessie harlow

Dalhousie University - Department of Physics and Atmospheric Science

roby gauthier

Dalhousie University - Department of Physics and Atmospheric Science

Jeff Dahn

Dalhousie University - Department of Physics and Atmospheric Science

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Abstract

An ultrasonic imaging technique has been developed to investigate the internal changes of pouch cells nondestructively. The local ultrasonic transmittance of pouch cells has been measured and used for imaging with a new ultrasonic scanning machine designed and built in-house. The wetting process of the cells is clearly observed via such ultrasonic imaging techniques. Furthermore, ultrasonic transmission images of fresh cells and aged cells with different electrolytes and cycling conditions exhibit very different ultrasonic transmittance, which can be caused by electrolyte dry-out or “unwetting” due to cell swelling. The ultrasonic imaging technique is a very sensitive method to probe failure mechanisms in Li-ion pouch cells.

Keywords: Lithium ion batteries, ultrasonic imaging, electrolyte wetting, electrolyte unwetting, failure mechanisms, state of health, aging

Suggested Citation

Deng, Zhe and Huang, Zhenyu and Shen, Yue and Huang, Yunhui and Ding, Han and Luscombe, Aidan and Johnson, Michel and harlow, jessie and gauthier, roby and Dahn, Jeff, Observation of the Electrolyte Wetting and 'Unwetting' in Li-Ion Pouch Cells Via Ultrasonic Scanning Technology. Available at SSRN: https://ssrn.com/abstract=3581362 or http://dx.doi.org/10.2139/ssrn.3581362
This version of the paper has not been formally peer reviewed.

Zhe Deng

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology

Wuhan, Hubei, 430074
China

Zhenyu Huang

Huazhong University of Science and Technology

1037 Luoyu Rd
Wuhan, Hubei 430074
China

Yue Shen

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology ( email )

Wuhan, Hubei, 430074
China

Yunhui Huang

Huazhong University of Science and Technology - State Key Laboratory of Material Processing and Die & Mould Technology ( email )

Wuhan, Hubei, 430074
China

Han Ding

Huazhong University of Science and Technology

1037 Luoyu Rd
Wuhan, Hubei 430074
China

Aidan Luscombe

Dalhousie University - Department of Physics and Atmospheric Science ( email )

Canada

Michel Johnson

Dalhousie University - Department of Physics and Atmospheric Science ( email )

Canada

Jessie Harlow

Dalhousie University - Department of Physics and Atmospheric Science ( email )

Canada

Roby Gauthier

Dalhousie University - Department of Physics and Atmospheric Science ( email )

Canada

Jeff Dahn (Contact Author)

Dalhousie University - Department of Physics and Atmospheric Science ( email )

Canada

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