Triarylamine-Enchained Semifluorinated Perfluorocycloalkenyl (PFCA) Aryl Ether Polymers

Appl Petrochem Res (2015) 5:35–45

11 Pages Posted: 13 Jul 2017

See all articles by Babloo Sharma

Babloo Sharma

University of Texas at Dallas

Mohammad Faisal

University of Texas at Dallas

Shawna Liff

Intel Corporation

Dennis Smith

University of Texas at Dallas

Date Written: February 25, 2016

Abstract

A variety of perfluorocycloalkenyl (PFCA) aryl ether monomers and polymers with enchained triarylamine units were successfully synthesized, characterized and reported here. These polymers are highly thermally stable and show variable thermal properties. Successful conver- sion of the newly synthesized TAA enchained perfluoro- cyclopentenyl (PFCP) aryl ether polymers via formylation and EAS demonstrates the synthetic versatility of TAA moiety and provides an excellent option for application specific post polymerization reactions. The cross-linking behavior of PFCP aryl ether polymers was studied under different reaction conditions. The combination of pro- cessability, thermal stabilities, and tailorability makes these polymers suitable for a wide variety of applications including electro-optics, proton exchange membranes and super-hydrophobic applications.

Keywords: Polymer, fluoropolymer, polycondensation, addition-elimination reaction, perfluorocycloalkene, perfluorocyclopentene, perfluorocyclohexene

JEL Classification: L60

Suggested Citation

Sharma, Babloo and Faisal, Mohammad and Liff, Shawna and Smith, Dennis, Triarylamine-Enchained Semifluorinated Perfluorocycloalkenyl (PFCA) Aryl Ether Polymers (February 25, 2016). Appl Petrochem Res (2015) 5:35–45. Available at SSRN: https://ssrn.com/abstract=2738205

Babloo Sharma (Contact Author)

University of Texas at Dallas ( email )

2601 North Floyd Road
Richardson, TX 75083
United States

Mohammad Faisal

University of Texas at Dallas

2601 North Floyd Road
Richardson, TX 75083
United States

Shawna Liff

Intel Corporation

United States

Dennis Smith

University of Texas at Dallas ( email )

2601 North Floyd Road
Richardson, TX 75083
United States

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