Li 2MNCL 4 an Efficient Nucleophile in Epoxide Ring Opening Reactions to Afford Synthesis of Chlorohydrins.

IJRAR November 2018, Volume 5, Issue 4

4 Pages Posted: 29 Jun 2019

See all articles by Santosh Devkate

Santosh Devkate

S. M. Joshi college Hadapsar

Arvind S. Burungale

affiliation not provided to SSRN

Sunil D. Jadhav

affiliation not provided to SSRN

Ashok S. Pise

affiliation not provided to SSRN

Ramesh B. Gawde

affiliation not provided to SSRN

Date Written: November 17, 2018

Abstract

The Li2MnCl4 reacts with epoxides to afford chlorohydrins resulting from attack at electron deficient carbon atom. The reaction works efficiently with chalcone oxide and yields are higher under nitrogen atmosphere.

Keywords: Activity spectra, dilithiumtetrachloromanganate, lithium chloride, homogeneous, chalcone oxide, epoxide

Suggested Citation

Devkate, Santosh and Burungale, Arvind S. and Jadhav, Sunil D. and Pise, Ashok S. and Gawde, Ramesh B., Li 2MNCL 4 an Efficient Nucleophile in Epoxide Ring Opening Reactions to Afford Synthesis of Chlorohydrins. (November 17, 2018). IJRAR November 2018, Volume 5, Issue 4 . Available at SSRN: https://ssrn.com/abstract=3401164

Santosh Devkate (Contact Author)

S. M. Joshi college Hadapsar ( email )

Hadapsar
Pune, MS 411028
India

Arvind S. Burungale

affiliation not provided to SSRN

Sunil D. Jadhav

affiliation not provided to SSRN

Ashok S. Pise

affiliation not provided to SSRN

Ramesh B. Gawde

affiliation not provided to SSRN

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