puc-header

Super-Stacking Self-Assembly of Organic Topological Heterostructure

27 Pages Posted: 8 Jan 2020 Sneak Peek Status: Under Review

See all articles by Ming-Peng Zhuo

Ming-Peng Zhuo

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Guang-Peng He

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Yi Yuan

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Yi-Chen Tao

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Guo-Qing Wei

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Xue-Dong Wang

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Shuit-Tong Lee

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

Liang-Sheng Liao

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

More...

Abstract

The precise control of multicomponent complex topological configurations (MCTCs) integrating more than one compound or one crystal-phase with high spatial and angular precision are extremely-challenging due to the anisotropic noncovalent interaction and the undesirable phase separation. Herein, we present a super-stacking self-assembly approach via adjusting the noncovalent interaction strength (| EBghiPE-TCNB (-3.14 kcal mol−1)| > | EBghiPE-TFP (-2.84 kcal mol−1)| > | EBghiPE-OFN (-2.15 kcal mol−1)| > | EBghiPE (-1.33 kcal mol−1)|) for the fine synthesis of molecular heterostructures with various photo-physical properties and low-dimensional morphologies, as well as phase heterostructures with multi-functional optoelectrical characteristics and multi-dimensional morphologies. Notably, the anisotropic noncovalent interaction and the lattice-matching principle facilitate the sequential crystallization and the horizontal/longitudinal growth in the crystal-puzzle process, respectively. This super-stacking self-assembly approach would be easily amenable to precise design and fine synthesis of the desirable organic MCTCs for the integrated optoelectronics.

Keywords: Fine synthesis, Noncovalent interactions, Super-stacking self-assembly, Organic topological heterostructure, Lattice-matching

Suggested Citation

Zhuo, Ming-Peng and He, Guang-Peng and Yuan, Yi and Tao, Yi-Chen and Wei, Guo-Qing and Wang, Xue-Dong and Lee, Shuit-Tong and Liao, Liang-Sheng, Super-Stacking Self-Assembly of Organic Topological Heterostructure. CHEMJOURNAL-D-19-01343. Available at SSRN: https://ssrn.com/abstract=3515383 or http://dx.doi.org/10.2139/ssrn.3515383
This is a paper under consideration at Cell Press and has not been peer-reviewed.

Ming-Peng Zhuo

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Guang-Peng He

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Yi Yuan

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM)

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Yi-Chen Tao

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Guo-Qing Wei

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Xue-Dong Wang (Contact Author)

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Shuit-Tong Lee

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Liang-Sheng Liao

Soochow University - Institute of Functional Nano and Soft Materials (FUNSOM) ( email )

No. 1 Shizi Street
Taipei, Jiangsu 215006
Taiwan

Click here to go to Cell.com

Paper statistics

Abstract Views
76
Downloads
4