A 10-Coordinate Cerium(Iii) Complex with a Ferrocene-Based Terpyridine Ligand Exhibiting Field-Induced Slow Magnetic Relaxation
19 Pages Posted: 1 Jun 2020
A novel cerium(III) complex [Ce(Fcterpy)(NO 3 ) 3 (H 2 O)]·DEE ( 1 ) (DEE = diethylether) bearing a substituted terpyridine ligand 4′-ferrocenyl-2,2′:6′,2″-terpyridine (Fcterpy) has been synthesized and characterized by single-crystal X-ray diffraction technique. Magnetic measurements revealed that complex 1 exhibits a single-ion magnet-like behaviour in the form of field-induced slow magnetic relaxation.
Keywords: Cerium(III), Ferrocene-based terpyridine, Field-induced, Slow Magnetic Relaxation
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