Advanced Energy-Saving Technology of Granular Nitrate-Containing NPK-Fertilizers

6 Pages Posted: 30 Jun 2020

Date Written: June 22, 2020

Abstract

There was developed the technology of granular balanced nitrate-containing NPK-fertilizers 16-16-16 and 17-17-17.

Key features of the proposed technology are:
- Joint ammoniation of a mixture of nitric and phosphoric acids to a molar ratio of NH3:H3PO4 1.4÷1.5 and complete-ammoniation in Ammoniatior-Granulator drum to 1.65÷1.8.
- Due to more efficient use of acid neutralization heat, the fluent slurry is obtained with low moisture content required for granulation.

Ammoniation of a mixture of nitric and phosphoric acids at higher molar ratio makes it possible to exclude the possibility of acidification of ammonium nitrate, which causes the process of self-accelerating decomposition.

The production of fertilizer grades with an increased molar ratio in the product have the following advantages:
- higher degree of WPA neutralization to a molar ratio of NH3:H3PO4 of 1.65÷1.8 mol / mol allows to reduce the consumption of nitric acid and to exclude the stage of forced evaporation of nitrate slurry and the stage of ammonium nitrate melt preparation;
- the cost of NPK-fertilizers with a lower content of ammonium nitrate is lower due to partial substitution of the nitrate nitrogen for ammonia nitrogen.
- improvement of physical and chemical properties of the final product due to reduction of nitrate nitrogen content,
- thermal stability of the obtained nitrate-containing NPK-fertilizers with an increased molar ratio in the product 1.65÷1.8;
- flexibility to obtain a broad range of NPK-fertilizer grades.

Keywords: NPK-fertilizers; ammonium nitrate; nitrate-containing; Ammoniatior-Granulator; thermal stability; NIUIF

Suggested Citation

Pagaleshkin, Denis and Kolpakov, Viacheslav, Advanced Energy-Saving Technology of Granular Nitrate-Containing NPK-Fertilizers (June 22, 2020). SYMPHOS 2019 – 5th International Symposium on Innovation & Technology in the Phosphate Industry, Available at SSRN: https://ssrn.com/abstract=3632985 or http://dx.doi.org/10.2139/ssrn.3632985

Denis Pagaleshkin (Contact Author)

JSC "NIUIF ( email )

Severnoe shosse 75,
Cherepovets, 162622
Russia

Viacheslav Kolpakov

JSC "NIUIF ( email )

Severnoe shosse 75,
Cherepovets, 162622
Russia

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