Traffic Light-Type Ratiometric Fluorescent Visual Sensing of Cs+ in Soybean Oil Based on Dimension Regulation of 2d Perovskite Nanosheets

Abstract

Determination of cesium ion in soybean oil is of high importance since the increasing risk from releasing of main component of nuclear waste cesium 137. The complex composition and high viscosity of soybean oil make it necessary to convert it into water phase by nitration before detection, so developing a simple, accurate and sensitive method for on-site sensing of Cs + in soybean oil is still a big challenge. In this work, we report a traffic light-type ratiometric fluorescent strategy for the visual sensing of Cs + in soybean oil based on dimensional regulation of two dimensional (PEA) 2 PbI 4 perovskite nanosheets (NSs). The PEA + in (PEA) 2 PbI 4 NSs exchanged with Cs + and lead to dimension of partial (PEA) 2 PbI4 NSs progressively increase from 2D to 3D CsPbI 3 NCs. Resultantly, the fluorescence of (PEA) 2 PbI 4 NSs decreases with a concomitant fluorescence enhancement of CsPbI 3 NCs upon increasing the concentrations of Cs + , and the emission accordingly change from green, yellow to red with a high fluorescence colorimetric resolution up to 5.0 μM, make it successful to achieve on-site sensing of Cs + in soybean oil just with naked eye in 5 min without any nitration, demonstrating a bright application future for determination of Cs + in the soybean oil.

Keywords: cesium, perovskite dimensional regulation, traffic light-type, fluorescence ratiometric sensing, soybean oil.