Experimental Characterization and Theoretical Investigation of Zn/Sm Co-Doped Hydroxyapatites

40 Pages Posted: 4 Apr 2022

See all articles by Niyazi Bulut

Niyazi Bulut

affiliation not provided to SSRN

Ala Hamd Hssain

affiliation not provided to SSRN

Tankut Ates

affiliation not provided to SSRN

Ali Kuruçay

affiliation not provided to SSRN

Hanifi Kebiroglu

affiliation not provided to SSRN

Omer Kaygili

affiliation not provided to SSRN

Suleyman Koytepe

Inonu Universitesi

Abstract

In this study, the wet chemical method was used to synthesize -doped hydroxyapatite  samples, and the effects of varying the amount of addition on structural, thermal, and biocompatibility in vitro properties were studied. In addition, the synthesized compounds were modeled in order to conduct theoretical research. and data confirmed the formation of biphasic compositions for all samples. More than  of samples showed the formation of  phase, whereas the minor phase was   Addition of  resulted in an increase in phase from  to  The lattice parameters unit cell volume lattice strain ), and lattice stress  varied when was added as a dopant. The crystallite size and crystallization percentage decreased as the  content increased, however, the anisotropic energy density gradually increased. Thermal analysis results confirmed that all samples seemed to be thermally stable. The addition of  did not result in any notable morphological modifications. Cell viability values of the -based  sharply decreased as a result of an increase in the  additive. Theoretical studies show that when the amount of in the -based  structure increases, the bandgap energy decreases from  to . An increasing density and decreasing unit cell volume have been observed, as confirmed by the theoretical results. In addition, there was a decrease in crystallinity as well as an increase in anisotropic energy density.

Keywords: Ion-substituted hydroxyapatite, Wet chemical method, Sm, Zn, Cell viability test

Suggested Citation

Bulut, Niyazi and Hssain, Ala Hamd and Ates, Tankut and Kuruçay, Ali and Kebiroglu, Hanifi and Kaygili, Omer and Koytepe, Suleyman, Experimental Characterization and Theoretical Investigation of Zn/Sm Co-Doped Hydroxyapatites. Available at SSRN: https://ssrn.com/abstract=4074587 or http://dx.doi.org/10.2139/ssrn.4074587

Niyazi Bulut (Contact Author)

affiliation not provided to SSRN ( email )

No Address Available

Ala Hamd Hssain

affiliation not provided to SSRN ( email )

No Address Available

Tankut Ates

affiliation not provided to SSRN ( email )

No Address Available

Ali Kuruçay

affiliation not provided to SSRN ( email )

No Address Available

Hanifi Kebiroglu

affiliation not provided to SSRN ( email )

No Address Available

Omer Kaygili

affiliation not provided to SSRN ( email )

No Address Available

Suleyman Koytepe

Inonu Universitesi ( email )

Malatya
Turkey

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