Synergistic Effects of Bimetallic Pd-Au(Alloy)/Sno2 Nanocomposites for Low Temperature and Selective Hydrogen Gas Sensors

Abstract

In view of the explosive nature of hydrogen gas, the demand for detection is increasing. Although Pd-based chemiresistive sensors are gaining much attention in hydrogen detection, it is easily oxidized at high temperatures, leading to the deterioration of sensing performance. To address this issue, we synthesized bimetallic Pd-Au alloy nanoparticles (NPs) and mixed them with SnO2 powder for improving the hydrogen sensing performance. The response of the bimetallic Pd-Au(alloy)/SnO2 nanocomposites (NCs) sensor toward 100 ppm hydrogen was 72.78 which is 7 times higher than that of the pure SnO2 sensor at a relatively lower working temperature of 150°C. Furthermore, when compared to other interfering gases, the sensor revealed high selectivity for hydrogen gas. The enhanced hydrogen sensing performance was attributed to the synergistic effect arising from the formation of a heterojunction interface between Pd-Au alloy and SnO2 NPs and the decomposition and absorption of hydrogen molecules by Pd-Au alloy NPs.

Keywords: metal oxide semiconductor, Pd-Au alloy, composite, Nanoparticle, Gas Sensor, hydrogen