Biochar for Supercapacitor Electrodes: Mechanisms in Aqueous Electrolytes

28 Pages Posted: 13 Feb 2023

See all articles by Wenyao Li

Wenyao Li

Shanghai University of Engineering Science

Caiyu Ma

Shanghai University of Engineering Science

Haiyun Cheng

Shanghai University of Engineering Science

Zhuangnan Li

University of Cambridge

Guanjie He

University College London

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Abstract

Utilizing biomass materials containing rich carbon-oxygen/nitrogen functional groups as precursors for synthesizing carbon materials is a promising strategy for energy storage and conversion applications. Porous biomass carbon materials are commonly used as the electric-double-layer capacitors in aqueous electrolytes. However, detailed kinetic analysis and energy storage mechanisms are seldom discussed and clarified. In this work, starch powders are modified with tunable nitrogen/oxygen functional groups during the KOH activation process to produce porous carbon. The kinetics and energy storage mechanism of this kind of material in acid and alkaline aqueous electrolyte are uncovered by in-situ ATR-IR in a three-electrode configuration.

Keywords: Biomass carbon, Electrode, Supercapacitor, In-situ ATR-IR

Suggested Citation

Li, Wenyao and Ma, Caiyu and Cheng, Haiyun and Li, Zhuangnan and He, Guanjie, Biochar for Supercapacitor Electrodes: Mechanisms in Aqueous Electrolytes. Available at SSRN: https://ssrn.com/abstract=4356107 or http://dx.doi.org/10.2139/ssrn.4356107

Wenyao Li (Contact Author)

Shanghai University of Engineering Science ( email )

shanghai, 201620
China

Caiyu Ma

Shanghai University of Engineering Science ( email )

shanghai, 201620
China

Haiyun Cheng

Shanghai University of Engineering Science ( email )

shanghai, 201620
China

Zhuangnan Li

University of Cambridge ( email )

Trinity Ln
Cambridge, CB2 1TN
United Kingdom

Guanjie He

University College London ( email )

Gower Street
London, WC1E 6BT
United Kingdom

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