Two Anthracene-Based Zirconium Metal–Organic Frameworks with Fcu and Hcp Topologies as Versatile Fluorescent Sensors for Detection of Inorganic Ions and Nitroaromatics

Abstract

Two anthracene-based zirconium metal-organic frameworks (UiO-68-AN-fcu and UiO-68-AN-hcp) with blue emission were synthesized by the solvothermal reaction of ZrCl4 with anthracene-based ligand 4,4'-(9,10-anthracenediyl)dibenzoic acid. The two MOFs inherited the luminescence properties of anthracene-based ligand and exhibited different topologies due to the change of connection mode of Zr-O clusters. The two stable anthracene-based zirconium MOFs served as luminescent sensors for selectively detecting 2-nitrophenol, Fe3+ and Cr2O72−. UiO-68-AN-hcp with flower morphology exhibited stronger quenching effect for 2-nitrophenol, Fe3+ and Cr2O72− by comparing to UiO-68-AN-fcu. Adsorption tests, fluorescence lifetime and spectroscopy studies demonstrated that the fluorescence responses of MOFs for analytes can be primarily attributed to the dynamic quenching mechanism involving energy and electron transfer. These results revealed that the combination of luminescent anthracene-based ligand and Zr-O clusters is a feasible strategy to construst MOFs-based fluorescent sensors.

Keywords: Anthracene-based zirconium metal-organic frameworks, Luminescent sensors, 2-nitrophenol, Fe3+ and Cr2O72− detection, Dynamic quenching mechanism