Dual-Emitting from Bi3+, Ln3+ (Ln = EU, Sm) Co-Activated Ca2sb2o7 Phosphor for Optical Temperature Measurement

Abstract

In this paper, a series of Ca(2- x - y )Sb2O7: xBi3+, yLn3+ (Ln=Eu, Sm) fluorescent powder samples were successfully obtained, which used the traditional high-temperature solid-phase synthesis method in the preparation process. Samples of Ca2Sb2O7: Bi3+, Ln3+ (Ln=Eu, Sm) fluorescent powder samples were structurally and optically characterised using X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM), photoluminescence excitation spectroscopy and emission spectroscopy, and fluorescence decay measurements. The results show that the prepared Ca(2- x - y )Sb2O7: xBi3+, yLn3+ (Ln = Eu, Sm) samples have an orthogonal spider web structure, which remains unchanged whether Bi3+is single doped or Bi3+ is co-doped with Ln3+ (Ln = Eu, Sm). Under ultraviolet lamp (λex = 340 nm) irradiation, Bi3+ doped Ca2Sb2O7 powder shows a wide emission band centered at 435 nm, which is owing to the 3P1→1S0 leap of Bi3+ ion. Therefore, the effect of Bi3+ and Ln3+ (Ln = Eu, Sm) co-doped Ca2Sb2O7 samples on the luminescence intensity of the samples at different concentrations was studied. When the temperature was varied from 293K to 483K, the absolute temperature sensitivity (Sa) of doped Bi3+/Eu3+ and Bi3+/Sm3+ phosphors is 0.001K−1 (at 483K) and 0.02K−1 (at 293K), respectively, and the relative temperature sensitivity (Sr) is 1.03% K−1 (at 343 K) and 1.19% K−1 (at 293 K), respectively. These results demonstrate that Ca(2- x - y )Sb2O7: xBi3+, yLn3+ (Ln = Eu, Sm) phosphors are prospective double emission thermal thermometers.

Keywords: Ca2Sb2O7, Luminescence performance, FIR, Temperature sensing