Constructing Sn0.1-Li4ti5o12/C for Li-Ion Batteries and Mg-Li Hybrid-Ion Batteries

16 Pages Posted: 28 Mar 2023

See all articles by keyan bao

keyan bao

Jiangsu University of Technology

Haowei Bian

Jiangsu University of Technology

Xinyue Zhang

Jiangsu University of Technology

Chao Ma

Jiangsu University of Technology

Jiaqi Zhang

Jiangsu University of Technology

Wutao Mao

Jiangsu University of Technology

Abstract

The Sn0.1-Li4Ti5O12/C (Sn0.1-LTO/C) composite, synthesized by the sol-gel method, exhibits excellent lithium storage performance. At a current rate of 1 C, the initial discharge specific capacity of Sn0.1-LTO/C reaches as high as 174.3 mAh g-1, maintained around 167.1 mAh g-1 after 200 cycles. Moreover, the capacity retention rate is still 81.4% after 1000 cycles. It is the carbon skeleton that provides a high conductivity and enables the Sn0.1-LTO/C an excellent electrochemical performance without the addition of a conductive agent in the preparation process. At a current rate of 5 C, the discharge specific capacity is 103 mAh g-1, and the capacity retention rate is 81.4 % after 1000 cycles. The performance of Sn0.1-LTO/C material as the cathode of Mg-Li dual-ion battery was comprehensively explored. At the current rate of 0.5 C, its first-cycle discharge specific capacity can reach 159.1 mAh g-1. This outstanding electrochemical performance is attributed to the synergy of Sn ion doping and the conductive carbon framework. Sn0.1-LTO/C composite generates promising application prospects in both Lithium-ion batteries and Mg-Lithium dual-ion batteries.

Keywords: Li4Ti5O12, Li-ion batteries, Mg-Li hybrid-ion batteries, structure design, electrochemical properties

Suggested Citation

bao, keyan and Bian, Haowei and Zhang, Xinyue and Ma, Chao and Zhang, Jiaqi and Mao, Wutao, Constructing Sn0.1-Li4ti5o12/C for Li-Ion Batteries and Mg-Li Hybrid-Ion Batteries. Available at SSRN: https://ssrn.com/abstract=4402637 or http://dx.doi.org/10.2139/ssrn.4402637

Keyan Bao (Contact Author)

Jiangsu University of Technology ( email )

China

Haowei Bian

Jiangsu University of Technology ( email )

China

Xinyue Zhang

Jiangsu University of Technology ( email )

China

Chao Ma

Jiangsu University of Technology ( email )

China

Jiaqi Zhang

Jiangsu University of Technology ( email )

China

Wutao Mao

Jiangsu University of Technology ( email )

China

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