A Study of the Properties of Hemicelluloses Adsorbed Onto Microfibrillar Cellulose Isolated from Apple Parenchyma

Abstract

Binding assays of commercially available hemicelluloses and pectins, and microfibrillar cellulose isolated form apple parenchyma were prepared. Initial studies showed that among all of the non-cellulosic polysaccharides examined, only the hemicelluloses (xyloglucan, xylan, glucomannan, ß-D-glucan) showed the ability to adsorb to microfibrillar cellulose. Among several adsorption models tested, the best fit was obtained for the Redlich-Peterson isotherm. Moreover, the linear vs. the branched structure and the size of the hemicelluloses have an influence over the extent of the adsorption to cellulose. The FTIR and Raman spectra showed that a rather weak interaction took place between the hemicelluloses and cellulose. Also, the differential scanning calorimetry and the light scattering method results showed that after adsorption, cellulose has less mobility. Moreover, the mechanical properties of cellulose films changed after the addition of the chosen hemicelluloses and the films became less elastic but more resistant to a breaking force.

Keywords: Cellulose, hemicellulose, Pectin, adsorption kinetic, adsorption isotherm, cellulose-hemicellulose composites