Study on the Temperature Rise Characteristics of Aging Lithium-Ion Batteries Under Different Cooling Methods

Abstract

Lithium-ion batteries have been widely used in electric vehicles and electrochemical energy storage power stations. With the increase of service time, the single cells in the battery module will age to varying degrees, resulting in uneven heat production and even safety accidents. In this paper, the uneven aging characteristics of different cells in small Lithium-ion battery modules and the temperature rise characteristics under different cooling conditions are investigated. The results show that the irreversible heat generation power of cell 1, cell 2 and cell 3 during 1 C discharge is 1.23 W, 1.33 W and 1.15 W, respectively, showing different degrees of aging. However, the maximum temperature rise under natural heat dissipation conditions has the same change trend and the average temperature rise on the surface of three cells at the end of discharge is about 20 °C. The temperature rise at the edge of cell 2 and cell 1 with more serious aging is higher, while the temperature rise at the center of cell 3 with the smallest aging degree is higher. The temperature distribution at different positions on the surface of the three cells was slightly different. The maximum temperature difference at different positions on the surface of cell 2 (2.3 °C) was greater than that of cell 1 (1.5 °C) and cell 3 (1.6 °C). Then, a simple OCV test method and SEM characterization technique were used to analyze the aging characteristics of the electrode position corresponding to the external temperature monitoring position of cell 2, and the relationship between temperature distribution and aging characteristics was established. The cooling and uniform temperature ability of thermal pad, semiconductor cooling and liquid cooling plate/semiconductor composite cooling are improved in turn. Among them, the liquid cooling plate/semiconductor composite cooling is an efficient temperature control strategy which can make the temperature of cell 3 basically stable at 23 ° C during 1C discharge by reasonably regulating the cooling power, and the maximum surface temperature difference is maintained at 0.4 ° C. It is suggested that when the large cell is put into use, it should be equipped with an independent sub-regional precise temperature control system that can adjust the cooling power in real time according to the heat production rate of the battery, so as to improve the safety and promote the development of sustainable energy.

Keywords: Lithium-ion batteries, Aging, Non-uniformity, Temperature distribution, Cooling methods