Rapid Characterization of Sulfur and Phosphorus in Organic Waste by Near Infrared Spectroscopy

Abstract

Near-infrared spectroscopy (NIRS) has recently emerged as a valuable tool for monitoring organic waste utilized in anaerobic digestion processes. Over the past decade, NIRS has significantly improved the characterization of organic waste by enabling the prediction of several crucial parameters such as biochemical methane potential, carbohydrate, lipid and nitrogen contents, Chemical Oxygen Demand, and kinetic parameters. This study investigates the application of NIRS for predicting the levels of Sulfur (S) and Phosphorus (P) within organic waste materials. The results for sulfur prediction exhibited a high level of accuracy, yielding an error of 1.21 g/Kg[TS] in an independently validated dataset, coupled with an R-squared value of 0.84. Conversely, the prediction of phosphorus proved to be slightly less successful, showing an error of 1.49 g/Kg[TS] with an R-squared value of 0.70. Furthermore, the disparities in performance seem to stem from the inherent correlation between the spectral data and the sulfur or phosphorus contents. Significantly, a variable selection technique known as Covsel was employed, shedding light on the differing approaches used for sulfur and phosphorus predictions. In the case of sulfur, the prediction was achieved through a direct correlation with wavelengths associated with sulfur-related functional groups (such as R−S(=O)2−OH, -SH, and R-S-S-R) present in the NIR spectra. In contrast, phosphorus prediction relied on an indirect correlation with absorption bands related to organic matter (including CH, CH2, CH3, -CHO, R-OH, C=O, -CO2H, and CONH).

Keywords: NIRS, waste characterization, Anaerobic co-digestion, Sulfur, Phosphorus, absorption bands.