Enhanced Heavy Metal Leaching from Volcanic Muds: Synergistic Effects of Citric Acid and Edta Composite System

Abstract

The soil leaching technology is a well-established technique commonly employed for the remediation of soils contaminated with heavy metals. Volcanic muds shares similar properties to those of soil. This study utilizes soil leaching technology to tackle the presence of heavy metals in volcanic muds. It examines the leaching removal effect of the synergistic system of organic acid citric acid (CA) and chelating agent EDTA on heavy metals Pb, Cd, Cr, and Ni in volcanic muds. The leaching conditions were initially selected and subsequently optimized through the application of response surface methodology (RSM). The priority of leaching conditions can be ranked as follows: leaching duration is found to be more crucial than leaching agent concentration, which is noted to be more pivotal than the solid-liquid ratio. Following an in-depth evaluation of model predictions and experimental validation, it has been established that the optimal leaching concentration of EDTA is 0.15  mol·L-1, the optimal leaching duration is 9 h, and the optimal solid-liquid ratio is 1:10. For the compound CA, the most effective leaching concentration is 0.3  mol·L-1, the optimal leaching duration is 8 h, and the optimal ratio of solid to liquid is 1:10. The significance of the leaching conditions was further explored in conjunction with RSM. Furthermore, the integration of both leaching methods, namely combined leaching and stepwise leaching, has been demonstrated to amplify the removal efficiency of heavy metals, with stepwise leaching showing the highest removal rate. The experimental findings suggest that the leaching technique involving CA and EDTA composite system is an effective approach for the remediation of heavy metals such as Pb, Cd, Cr, and Ni in volcanic muds. This study provides theoretical rationale for the adoption of soil leaching technology in the remediation of heavy metals in volcanic muds. Additionally, the heavy metal content of the remediated volcanic muds substantially meets with the standards for cosmetic raw materials.

Keywords: Volcanic mud, Soil leaching, EDTA, Response surface methodology