Fe3co Nanoparticles Embedded Carbon Nanotube Complex as Effective Bifunctional Electrocatalysts for Rechargeable Zinc-Air Batteries

Abstract

Fe3Co nanoparticles have been successfully embedded within ZIF-8 derived carbon nanotube complex using a simple solvent-heated self-assembly-pyrolysis strategy, it acts as an efficient ORR/OER bifunctional electrocatalyst and showed outstanding performance of excellent catalytic activity for ORR (E1/2=0.87V at 0.1M KOH) and OER (the overpotential at 10 mA cm-2 is 390 mV at 1 M KOH). Density functional theory (DFT) demonstrates that the introduction of iron and cobalt atoms significantly impacted on the adsorption energies of the reactive intermediates. In particular, the combination of cobalt and iron exhibited significantly enhanced ORR/OER activities, revealing an enhanced effect of synergistic interaction of FeCo site for bifunctional properties. It is used as Fe3Co1−NC in aqueous zinc-air battery (ZAB) and exhibited a high open-circuit voltage of 1.52 V, power density of 189.8 mW cm-2, and long cycle durability of 400 h. Flexible ZABs assembled exhibit high power density (81.59 mW cm-2) and long cycling durability (90 h).

Keywords: ZIF-8, carbon nanotube, Fe3Co embedment, flexible zinc-air batteries, high power density