Rheological Behavior of Molybdenum Disulfide (MoS ₂) Inks Under Electric Fields: Influence of Concentration and Voltage

Abstract

This work provides a complete rheological characterization of molybdenum disulfide (MoS2) inks in the presence of electric fields. Several concentrations of MoS2 are studied and dispersed in a viscoelastic fluid. The lubrication effects are present in the ink when the MoS2 concentration is higher than 0.10% w/w. The dielectric properties show the impossibility of a positive electrorheological effect for all MoS2-inks studied. The formation of vortices and electromigration of MoS2 particles occur under the influence of an external electric field. These two phenomena affect the rheological behavior of MoS2-inks under shear flow condition. Relatively to the extensional rheology experiments, the particle migration and the vortex formation promote anisotropy on the rheological properties of the inks which affects the relaxation time, the formation of beads-on-a-string and the uniaxial elongational flow condition is no longer valid. When the electric field strength is 1.5 kV/mm, the formation of Taylor’s cone is observed and independent of MoS2 concentration.

Keywords: molybdenum disulfide, 2D nanoparticles, viscoelastic fluid, electric field, shear rheology, extensional rheology